To determine enthalpy change of hydration of magnesium sulphatevi essay

Ammonium hydroxide solution In the strong acid-weak base titration, 0. Ammonium hydroxide was then titrated slowly into the conical flask and the conical flask was swirled gently to ensure the reaction is Among these, aminated hyper cross linked polymers display a unique advantage in adsorption of aromatic sulphonates Pan et al.

Written by Rachel Buckley Abstract This experiment, Enthalpy of Hydration, is used to calculate the enthalpy of hydration of magnesium sulfate by measuring the temperature change of both anhydrous magnesium sulfate and hydrated magnesium sulfate when they are added separately to two different calorimeters and allowed to react.

The results are then used to calculate the enthalpy of hydration. Methods and Materials First, one sample of anhydrous, between 7 and 8 grams, and one sample of hydrate, between Then, a weighed polystyrene cup was obtained and filled with mL of distilled water.

The thermometer attached to the Palm Pilot was then placed in the water and allowed to obtain measurements for 5 minutes. After five minutes, the anhydrous was rapidly added to the water, which was constantly being stirred, and allowed to react for an additional 8 minutes, or until the temperature became pretty constant.

The Palm Pilot recorded the temperature every thirty seconds during this time period. The same process was repeated with the hydrate, using new distilled water.

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Observations and Discussions The graph above shows the change in temperature over a minute time period for the reaction of the anhydrous magnesium sulfate. The jump in the graph represents the time at which the anhydrous was added to the distilled water.

The water eventually started cooling back down after it heated up due to the dissolution of the anhydrous that was added to the water. The increase in temperature indicates that the reaction involved is exothermic, thus releasing energy and heating up. The temperature change over the whole reaction was 9.

The heat capacity of the system was found by multiplying the mass of the anhydrous plus the mass of the water, Once heat capacity was calculated, it was plugged into the equation above.

The calculated heat change of the reaction was This number was then divided by the number of moles of solute to find the enthalpy of dissolution, which ended up being The graph above shows the temperature over a minute period for the reaction of the hydrated magnesium sulfate.

The dip in the graph was due to the addition of the hydrate after five minutes of the water adjusting. The decrease in temperature represents the fact that the hydrate requires energy to dissolve, thus the reaction is an endothermic reaction.

The change in temperature for the reaction was The heat of dissolution was calculated in the same manner as it was for the anhydrous, where the mass of the hydrate mixture was This number was divided by 0.

This yields the enthalpy of dissolution, which was Finally, to find the enthalpy of hydration, the enthalpy of dissolution of the hydrate was subtracted from the enthalpy of dissolution of the anhydrous.

Enthalpy Change of the Hydration of Magnesium Sulphate | Essay Example

The calculated enthalpy of hydration for this experiment was The enthalpy of dissolution of the hydrate can be added to the enthalpy of hydration of the overall reaction to find the enthalpy of dissolution of the anhydrous, so that equation can be rearranged such that the enthalpy of dissolution of the hydrate may be subtracted from the enthalpy of dissolution of the anhydrous to find the enthalpy of hydration for the overall reaction.

This law is advantageous due to the fact that enthalpies of hydration are difficult to measure directly. Conclusion The experiment performed, Enthalpy of Hydration, was used to determine the enthalpy of hydration of an anhydrous magnesium sulfate sample.

This was found by measuring the temperature change over a period of time for a reaction of water and the anhydrous sample, as well as the reaction of a hydrated magnesium sulfate sample.

The end result yielded the enthalpy of There are no known exact enthalpies of hydration, due to the fact that they are difficult to measure directly.Determining an enthalpy change of a displacement reaction Aim: To determine the enthalpy change for the displacement reaction between zinc powder and copper (II) sulphate solution.

Introduction Enthalpy of hydration is the energy change for converting 1 mol of an anhydrous substance to 1 mol of the hydrated substance. In order to find this number, it is necessary to first calculate the enthalpy of dissolution for each substance separately, and then find the different between the two.

Enthalpy Change of the Hydration of Magnesium Sulphate Essay Sample. Objective. To determine the enthalpy change of the hydration of magnesium sulphate (MgSO4) using Hess’s law.

Procedures. 1. The mass of a clean and dry polystyrene foam cup was weighed and recorded. 2. cm3 of de-ionized water was measured by using a . Objective To determine the enthalpy change of the hydration of magnesium sulphate (MgSO4) using Hess's law.

Procedures 1. The mass of a clean and dry polystyrene foam cup was weighed and recorded. The students repeated the experiment using g of solid hydrated magnesium sulfate, MgSO4•7H2O (s), and cm3 of water. They found the enthalpy change, ΔH2, to be +18 kJ mol−1. The enthalpy of hydration of solid anhydrous magnesium sulfate is difficult to determine experimentally, but can be determined using the diagram below.

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Enthalpy Change of the Hydration of Magnesium Sulphate Essay Sample. Objective. To determine the enthalpy change of the hydration of magnesium sulphate (MgSO4) using Hess’s law. Procedures.

Enthalpy of Hydration Lab Analysis	The mass of a clean and dry polystyrene foam cup was weighed and recorded.
Enthalpy Change of the Hydration of Magnesium Sulphate Essay Sample	Energy change per mole of anhydrous magnesium sulphate? Using the enthalpy changes of the reactions calculated above, construct an energy cycle and determine the enthalpy change of the hydration of magnesium sulphate.
Using Hess's Law to Calculate Enthalpy Change | Essay Example	Calculations To find the mass of water used, I subtracted the weight of the cup with just the stirring rod from the weight of the cup with the stirring rod and water.
Enthalpy Change of the Hydration of Magnesium Sulphate | Essay Example	Ammonium hydroxide solution In the strong acid-weak base titration, 0. Ammonium hydroxide was then titrated slowly into the conical flask and the conical flask was swirled gently to ensure the reaction is
Using Hess’s Law to Calculate Enthalpy Change Essay Sample	Add algebraically the chemical equations of reactions 1 and 3.

1. The mass of a clean and dry polystyrene foam cup was weighed and recorded. 2. cm3 of de-ionized water was measured by using a measuring cylinder. 3.